Catalytic-Level Identification of Prepared Pt/HY, Pt-Zn/HY, and Pt-Rh/HY Nanocatalysts on the Reforming Reactions of N-Heptane
نویسندگان
چکیده
The operation of reforming catalysts in a fixed bed reactor undergoes high level interaction between the operating parameters and reaction mechanism. Understanding such an reduces catalyst deactivation rate. In present work, three kinds nanocatalysts (i.e., Pt/HY, Pt-Zn/HY, Pt-Rh/HY) were synthesized. catalysts’ performances evaluated for n-heptane reactions reactor. conditions applied following: 1 bar pressure, WHSV 4, hydrogen/n-heptane ratio temperatures 425, 450, 475, 500, 525 °C. optimal temperature all types to produce high-quality isomers aromatic hydrocarbons was 500 Accordingly, nanocatalyst Pt-Zn/HY provided highest catalytic selectivity desired hydrocarbons. Moreover, Pt-Zn/HY-nanocatalyst showed more resistance against comparison with other two (Pt/HY Pt-Rh/HY). This work offers understanding application process petroleum refineries performance economic feasibility.
منابع مشابه
Determination of Activity and Selectivity of n-Heptane by Reforming Catalytic Pt-V Supported on gamma-Alumina
Bimetallic Pt-V supported by Gamma-alumina is used to observe the changes of nheptanewhen passed over this catalyst. The Pt concentration was kept constant at0.1wt% while the concentration of the vanadium was 0.5wt%. The activity andselectivity of catalyst have been determined under conditions at 450-500 degreescentigrade and 15-30 attn. The experimental results show that the addition of second...
متن کاملConversion of N-Heptane on Pt/Al2O3 Catalyst
Hydrogenation reaction with n-heptane on Pt/Al2O3 catalyst was investigated under the steady state condition in a fixed bed reactor. The catalyst was prepared under a variety of conditions, but the one chosen was non-acidic that is not considered a hydrocracking catalyst. The main objective was to vary the selectivity of n-heptane as a function of reaction variables es...
متن کاملInvestigation of Activity and Selectivity of n-Heptane by Reforming Pt-Ta Catalyst Supported on y-Alumina
The catalyst Pt-Ta supported on 7-alumina was prepared by impregnation with solution containing compoundsof II21K1.0. and Ta205 The Pt concentration was kept constant at 0.2 vet% while the concentration of thetantalum was 0,4 wt%. The activity and selectivity of catalyst were determined under conditions at 450-500 °Cand 15-30 atm.. with molar ratio H2/C[H,e5 and WH=1.5mL/h for converted n-hepta...
متن کاملdetermination of activity and selectivity of n-heptane by reforming catalytic pt-v supported on gamma-alumina
bimetallic pt-v supported by gamma-alumina is used to observe the changes of nheptanewhen passed over this catalyst. the pt concentration was kept constant at0.1wt% while the concentration of the vanadium was 0.5wt%. the activity andselectivity of catalyst have been determined under conditions at 450-500 degreescentigrade and 15-30 attn. the experimental results show that the addition of second...
متن کاملKinetic Study and Modelling of n-Heptane Reforming Process over Pt/Zr-HMS/HZSM-5 Composite Catalysts
Pt/Zr(x)-HMS/HZSM-5 catalysts with various Si/Zr ratios (as x) were used for investigation of the kinetics of n-heptane reforming process under 350 - 450 oC reaction temperature, 35 to 80 ml min-1 flowing rate of hydrogen and 2 to 5 ml h-1 flowing rate of n-heptane. In the present work, two kinetics (power law and Langmuir - Hinshelwood) models were selected and examined to describe the kinetic...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Processes
سال: 2023
ISSN: ['2227-9717']
DOI: https://doi.org/10.3390/pr11010270